Anne Shirley - Now a student at Redmond College, Anne has become an elegant, smart young woman.
Marilla Cuthbert - The stern, upright woman who took Anne in when she was just a girl, Marilla has now become a loving mother figure to Anne. She continues to live at Green Gables with the twins, Davy and Dora Keith who are her dead second cousins children.
Gilbert Blythe - Anne's childhood rival and now good friend. Gilbert is now studying at Redmond College and is in Anne's class. After many years, he finally admits his love for Anne and proposes to her. He is rejected the first time but after falling ill and proposing again Anne accepts it.
Charlie Sloane - An old schoolmate who has feelings for Anne, but who Anne has always felt indifferent towards and is now in her class at Redmond College. He proposes to Anne but is rejected.
Priscilla Grant - Anne's friend from Queen's Academy, Priscilla is one of Anne's roommates at Patty's Place.
Stella Maynard - Anne's friend from Queen's Academy, Stella is one of Anne's roommates at Patty's Place.
Philippa Gordon - Anne's new friend from Redmond College, Philippa (or Phil for short) is playful and charming and can't choose between her beaus. However, she is also a loyal friend and plays an essential role in bringing Anne and Gilbert together at the end.
Royal Gardner - A handsome Redmond student who Anne at first thinks is her dream man having become friends after he shared his umbrella with her. He courts Anne for two years. Anne is at first enamored by his romantic gestures, but eventually finds him rather dull and humorless and rejects his proposal.
Diana Barry - Anne's kindred spirit since childhood. The two remain best friends, even as Diana marries and starts a family.
Davy Keith - One of the twins who Marilla took in, Davy is mischievous but sweet at heart, and idolizes Anne. He has fair, fuzzy ringlets all over his head, one dimple, roguish hazel eyes, a snub nose and is often smiling.
Dora Keith - Dora, Davy's sister, is completely the contrary of her brother. She does everything she is told without mistake and is very docile. She has sleek curls, hazel eyes, a straight nose and "prunes and prisms" mouth.
Rachel Lynde - Formerly Marilla and Anne's neighbour, who has since moved to Green Gables after the death of her husband Thomas. While she is outspoken and demanding, she is well-intentioned and kindhearted.
Ruby Gillis - Anne's childhood friend. Ruby is fair and beautiful and prepared to marry when she discovers that she is gravely ill and dies later in the book.
Jane Andrews - Anne's childhood friend. Jane is a teacher who meets and marries an older millionaire, much to Mrs. Andrews' delight.
Billy Andrews - Jane's slow-witted brother, who is Anne's first proposal. Too bashful to go courting, he uses his sister as an intermediary. Anne is disappointed but amused at how unromantic the whole situation and she rejects him.
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